Kim Zolciak-Biermann has been married to her husband Kroy Biermann. According to some sources, Kim Zolciak Biermann husband Kroy Biermann has studied Criminology and Psychology at the University of Montana. To those who do not know who Kim Zolciak-Biermann is, she is an American television personality and singer. She is famous for appearing on the reality TV series The Real Housewives of Atlanta. Here are some facts about Kim Zolciak-Biermann’s husband Kroy Biermann. Kim Zolciak-Biermann also said that their children listen to her husband better that they listen to her. It seems the children are closer and attached to their father.